TY - GEN
T1 - Al-doped ZnO film as a transparent conductive substrate in indoline-sensitized nanoporous ZnO solar cell
AU - Onwona-Agyeman, B.
AU - Nakao, M.
AU - Kumara, G. R.A.
AU - Kitaoka, T.
PY - 2013
Y1 - 2013
N2 - We have deposited porous ZnO films on aluminum-doped ZnO (ZnO/AZO) and fluorine-doped tin oxide (ZnO/FTO) transparent substrates, and annealed both in air at 500°C. X-ray diffraction measurements of the nanoporous ZnO films after heat treatment showed that, ZnO/AZO film exhibited a dominant (002) diffraction while the ZnO/FTO showed mixed diffraction peaks with the (100) and (101) being dominant. Dye-sensitized solar cells (DSC) based on the sensitization of the porous ZnO films on AZO and FTO substrates with an indoline dye were constructed. The photoaction spectrum, which is a measure of the degree of sunlight harvesting, was broad and higher in the ZnO/AZO DSC than that of the ZnO/FTO DSC. Conversion efficiency of 7.3% was obtained for the ZnO/AZO DSC while 4.5% was recorded for the ZnO/FTO. The superior photovoltaic performance of the ZnO/AZO DSC is attributed to better ZnO film orientation after thermal treatment and the higher sunlight harvesting.
AB - We have deposited porous ZnO films on aluminum-doped ZnO (ZnO/AZO) and fluorine-doped tin oxide (ZnO/FTO) transparent substrates, and annealed both in air at 500°C. X-ray diffraction measurements of the nanoporous ZnO films after heat treatment showed that, ZnO/AZO film exhibited a dominant (002) diffraction while the ZnO/FTO showed mixed diffraction peaks with the (100) and (101) being dominant. Dye-sensitized solar cells (DSC) based on the sensitization of the porous ZnO films on AZO and FTO substrates with an indoline dye were constructed. The photoaction spectrum, which is a measure of the degree of sunlight harvesting, was broad and higher in the ZnO/AZO DSC than that of the ZnO/FTO DSC. Conversion efficiency of 7.3% was obtained for the ZnO/AZO DSC while 4.5% was recorded for the ZnO/FTO. The superior photovoltaic performance of the ZnO/AZO DSC is attributed to better ZnO film orientation after thermal treatment and the higher sunlight harvesting.
UR - http://www.scopus.com/inward/record.url?scp=84889261682&partnerID=8YFLogxK
U2 - 10.1557/opl.2012.1646
DO - 10.1557/opl.2012.1646
M3 - Conference contribution
AN - SCOPUS:84889261682
SN - 9781605114712
T3 - Materials Research Society Symposium Proceedings
SP - 345
EP - 350
BT - Oxide Semiconductors and Thin Films
T2 - 2012 MRS Fall Meeting
Y2 - 25 November 2012 through 30 November 2012
ER -